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Dessert

Chocolate Caramels

A sweet confection made by cooking chocolate, sugar, water, butter, vinegar, and vanilla until brittle.

From an old cookbook · modernised transcription
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Why it works: Chocolate and vanilla are a kitchen classic. They rank in the top 5% of all ingredient pairs, and cooks put them together in 10,020 recipes. Both carry sotolon, which smells curry, maple. The science ↓

Chocolate Caramels

Ingredients

Directions

Make the caramel

  1. In a saucepan, combine grated chocolate, brown sugar, cold water, butter, and vinegar.

  2. Cook over a brisk fire without stirring, gently shaking the vessel.

  3. Boil until the mixture becomes brittle when tested in water.

Set and cut

  1. Pour into a well-buttered and floured dripping pan.

  2. Cut into squares while still soft.

Recipe from a historical cookbook (Internet Archive).

Transcribed from a scanned cookbook and modernised for today's kitchens. Where the book gave no heat or time, or said "a moderate oven", the temperatures and times here may be modern equivalents rather than the book's own figures.

Explore the science

The flavor team

The pairs that carry this dish. Each one is judged two ways: how much their aromas overlap, and how often cooks already put them together.

  1. Chocolate + vanillatop 5% of all pairs
    Smell alikemoderate
    Cooked together10,020 recipes

    Shared aroma: sotolon (curry, maple).

  2. Sugar + vanillatop 8% of all pairs
    Smell alikelow
    Cooked together35,032 recipes

    Shared aroma: beta-damascenone (apple, rose).

  3. Chocolate + sugartop 13% of all pairs
    Smell alikemoderate
    Cooked together15,404 recipes

    Shared aroma: guaiacol (smoky, sweet).

  4. Butter + vanillatop 14% of all pairs
    Smell alikemoderate
    Cooked together20,050 recipes

    Shared aroma: guaiacol (smoky, sweet).

  5. Sugar + vinegartop 15% of all pairs
    Smell alikemoderate
    Cooked together20,806 recipes

    Shared aroma: beta-damascenone (apple, rose).

Sugar and vanilla barely smell alike, yet cooks put them together in 35,032 recipes: they work on texture and structure more than aroma.

Ranks compare each pair with 20,000 random ingredient pairs on CompKitchen. How we score pairs

What each ingredient does

Brown sugar
Provides sweetness and the body that the caramel sets around as it cools.
Grated chocolate
Adds chocolate flavour and fat, giving the caramel its color and richness.
Butter
Adds fat for a softer, smoother bite and a rich flavour.
Vinegar
Adds a slight acidity that helps keep the sugar from crystallising too early.

The step that matters

Boil until brittle in water. Sugar candy sets firm only once enough water has boiled off and the sugar concentration is high. Stopping too early leaves the caramels sticky and soft; cooking too long makes them hard and tough to cut.

“What each ingredient does” and “The step that matters” were written by Claude from this recipe’s own method and reviewed in samples by CompKitchen.

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